IMPARTING SUPERHYDROPHOBICITY OF POLYESTER FABRICS WITH CONTROLLED RELEASE USING SIO2 AEROGEL MICROCAPSULE COATING

Authors

  • MD SHARIFUL ISLAM, College of Textiles and Clothing, Qingdao University, Qingdao, 266071, China, Author
  • KHURSHID ALAM College of Textiles and Clothing, Qingdao University, Qingdao, 266071, China, Author
  • MST ATIA RABBI College of Textiles and Clothing, Qingdao University, Qingdao, 266071, China Author
  • SHAHARIA AHMED College of Textiles and Clothing, Qingdao University, China Author

DOI:

https://doi.org/10.63456/tsrj-2-1-28

Keywords:

Sio2 Aerogel Microcapsule, Superhydrophobic Coating, Diffusion-Controlled Release, Multifunctional Polyester, Wash Durability

Abstract

Developing polyester fabrics that combine fragrance release with durable liquid repellency remains a challenge in smart textiles. In this research, we introduce a novel dual-functional finishing technique that merges SiO2 aerogel microcapsule coating with Triethoxy-1H,1H,2H,2H-tridecafluorooctylsilane (POTS) to produce superhydrophobic aromatic polyester fabrics. Scanning Electron Microscopy (SEM) confirmed uniform adhesion of approximately 10 μm microcapsules, optimally dispersed at 10 wt%. The resultant polyester fabrics achieved water contact angles above 150°, demonstrated strong self-cleaning properties, and resisted wetting by both water-based and oily liquids. As microcapsule content increased, air and moisture permeability decreased due to pore blocking, indicating a balance between protection and breathability. Despite this, the fabrics effectively released fragrance, with 15.8% of essential oil released after 30 h at 80 °C, comparable to isolated SiO2 microcapsules. Additionally, the fabric handle experiment exhibited reduced softness and smoothness but increased stiffness and drape coefficient with higher microcapsule amounts. Moreover, washing durability performance indicated gradual microcapsule loss and decreased hydrophobicity, although partial repellency and fragrance retention persisted after 20 cycles. Consequently, these findings demonstrate a potential finishing process for producing multifunctional polyester fabrics suitable for smart and protective textile applications.

References

[1]

S. Ahmed, S. Du, H. Huang, Z. Qu, T. Zha, Y. Li, M. Mei, Y. Zhang, S. Mei, X. Li, F. Qin, W. Zhou, Glycolysis Products Recycled From Waste PET Bottles for Low Temperature Carrier-Assisted Dyeing of Polyester Fabrics, J. Appl. Polym. Sci. 142 (2025) e57562. https://doi.org/10.1002/app.57562.

[2]

J. Ma, J. Fan, Y. Xia, X. Kou, Q. Ke, Y. Zhao, Preparation of aromatic β-cyclodextrin nano/microcapsules and corresponding aromatic textiles: A review, Carbohydr. Polym. 308 (2023) 120661. https://doi.org/10.1016/j.carbpol.2023.120661.

[3]

U. Pithanthanakul, S. Vatanyoopaisarn, B. Thumthanaruk, C. Puttanlek, D. Uttapap, B. Kietthanakorn, V. Rungsardthong, Encapsulation of fragrances in zein nanoparticles and use as fabric softener for textile application, Flavour Fragr. J. 36 (2021) 365–373. https://doi.org/10.1002/ffj.3648.

[4]

Z. Xiao, H. Liu, Q. Zhao, Y. Niu, Z. Chen, D. Zhao, Application of microencapsulation technology in silk fibers, J. Appl. Polym. Sci. 139 (2022) e52351. https://doi.org/10.1002/app.52351.

[5]

B. Golja, P.F. Tavčer, Patterned Printing of Fragrant Microcapsules to Cotton Fabric, Coatings 12 (2022) 593. https://doi.org/10.3390/coatings12050593.

[6]

S. Khanna, S. Sharma, J.N. Chakraborty, Performance assessment of fragrance finished cotton with cyclodextrin assisted anchoring hosts, Fas Text 2 (2015) 19. https://doi.org/10.1186/s40691-015-0042-9.

[7]

V.O.C. Concha, J.O. Bahú, S. Crivellin, N.G. Khouri, F.L. Munoz, S.D.A. Souza, M.C.P. Yoshida, P. Severino, L.S.C. Concha, M.S. Lopes, E.B. Souto, Harnessing electrospinning for improvement of polymeric drug delivery systems, Polym. Bull. 82 (2025) 5909–5943. https://doi.org/10.1007/s00289-025-05710-w.

[8]

H. Chen, L. Li, Y. Ma, T.P. Mcdonald, Y. Wang, Development of active packaging film containing bioactive components encapsulated in β-cyclodextrin and its application, Food Hydrocolloids 90 (2019) 360–366. https://doi.org/10.1016/j.foodhyd.2018.12.043.

[9]

Z. Ye, S. Li, S. Zhao, L. Deng, J. Zhang, A. Dong, Textile coatings configured by double-nanoparticles to optimally couple superhydrophobic and antibacterial properties, Chem. Eng. J. 420 (2021) 127680. https://doi.org/10.1016/J.CEJ.2020.127680.

[10]

D. Stan, A.M. Enciu, A.L. Mateescu, A.C. Ion, A.C. Brezeanu, C. Tanase, Natural Compounds With Antimicrobial and Antiviral Effect and Nanocarriers Used for Their Transportation, Front. Pharmacol. 12 (2021) 723233. https://doi.org/10.3389/fphar.2021.723233.

[11]

J.D. Ogilvie-Battersby, R. Nagarajan, R. Mosurkal, N. Orbey, Microencapsulation and controlled release of insect repellent geraniol in gelatin/gum arabic microcapsules, Colloids Surf. A 640 (2022) 128494. https://doi.org/10.1016/j.colsurfa.2022.128494.

[12]

Y. Zhan, S. Yu, A. Amirfazli, A. Rahim Siddiqui, W. Li, Recent Advances in Antibacterial Superhydrophobic Coatings, Adv. Eng. Mater. 24 (2022) 2101053. https://doi.org/10.1002/ADEM.202101053.

[13]

K. Taliantzis, K. Ellinas, Green hydrophobic and superhydrophobic coatings and surfaces for water related applications: A review, Adv. Colloid Interface Sci. 343 (2025) 103566. https://doi.org/10.1016/j.cis.2025.103566.

[14]

S. Sfameni, T. Lawnick, G. Rando, A. Visco, T. Textor, M.R. Plutino, Super-Hydrophobicity of Polyester Fabrics Driven by Functional Sustainable Fluorine-Free Silane-Based Coatings, Gels 9 (2023) 109. https://doi.org/10.3390/gels9020109.

[15]

M. Huang, J. Yang, Long-term performance of 1H, 1H′, 2H, 2H′-perfluorooctyl triethoxysilane (POTS) microcapsule-based self-healing anticorrosive coatings, J. Intell. Mater. Syst. Struct. 25 (2013) 98–106.

[16]

L.J. Xu, X.Y. Shi, M.Y. Chai, J. Ji, Z.K. Xu, L.S. Wan, Surface Metallization of Porous Polymer Materials for Multifunctional Applications, Langmuir 36 (2020) 1454–1461. https://doi.org/10.1021/ACS.LANGMUIR.9B03701.

[17]

T. He, X. Chen, Y. Wang, Z. Cheng, Y. Liu, X. Wang, L. Luo, Y. Chen, X. Liu, Fabrication of durable superhydrophobic surfaces of polyester fabrics via fluorination-induced grafting copolymerization, Appl. Surf. Sci. 515 (2020) 146006. https://doi.org/10.1016/j.apsusc.2020.146006.

[18]

J. Landsiedel, J. Tschannett, M. Lenninger, S. Stroj, M. Domke, T. Bechtold, T. Pham, N. Aguiló-Aguayo, A siloxane interlayer approach to enhance surface metallization on polyamide fabrics via electroless copper deposition, Surf. Interfaces 42 (2023) 103434. https://doi.org/10.1016/J.SURFIN.2023.103434.

[19]

Y. He, L. Wang, T. Wu, Z. Wu, Y. Chen, K. Yin, Facile fabrication of hierarchical textures for substrate-independent and durable superhydrophobic surfaces, Nanoscale 14 (2022) 9392–9400. https://doi.org/10.1039/D2NR02157A.

[20]

Y. Zhang, X. Xia, K. Ma, G. Xia, M. Wu, Y.H. Cheung, H. Yu, B. Zou, X. Zhang, O.K. Farha, J.H. Xin, Functional Textiles with Smart Properties: Their Fabrications and Sustainable Applications, Adv. Funct. Mater. 33 (2023) 2301607. https://doi.org/10.1002/ADFM.202301607.

[21]

M. Yan, Y. Pan, P. He, L. Gong, Y. Fu, X. Cheng, Hyperelastic and multifunctional SiC/SiO₂ composite aerogels with excellent mechanical, thermal insulation and electromagnetic wave absorbing properties, Compos. Part A 186 (2024) 108408. https://doi.org/10.1016/j.compositesa.2024.108408.

[22]

N.R. Khan, T. Sharmin, A. Bin Rashid, Exploring the Versatility of Aerogels: Broad Applications in Biomedical Engineering, Astronautics, Energy Storage, Biosensing, and Current Progress, Heliyon 10 (2024) e23102. https://doi.org/10.1016/J.HELIYON.2023.E23102.

[23]

Y.W. Liu, Z.S. Nong, T.N. Man, S.W. Lu, L.H. Dong, SiO₂ aerogel coating with organic montmorillonite compounded with flame retardants: A strategy for design of a multifunctional thermal barrier coating, J. Mater. Res. Technol. 30 (2024) 318–331. https://doi.org/10.1016/j.jmrt.2024.03.083.

[24]

X.T. Xuan, H. Zhang, H.L. Wang, J. Le Yao, J. Xu, Q.L. Che, Y. Wang, One-step hydrothermal fabrication of COF/SiO₂/POTS composite coating on cellulose-based cotton fabrics with superhydrophobic self-cleaning, light-induced color change, and self-healing anti-icing properties, Int. J. Biol. Macromol. 329 (2025) 147756. https://doi.org/10.1016/J.IJBIOMAC.2025.147756.

[25]

W. Li, K. Liu, Y. Zhang, S. Guo, Z. Li, S.C. Tan, A facile strategy to prepare robust self-healable superhydrophobic fabrics with self-cleaning, anti-icing, UV resistance, and antibacterial properties, Chem. Eng. J. 446 (2022) 137195. https://doi.org/10.1016/j.cej.2022.137195.

[26]

R. Wang, P. Xiao, B. Yu, Y. Sun, J. Li, L. Zhang, X. Jiang, W. Wu, Fluorination Effects on the Drug Delivery Property of Cylindrical Polymer Brushes, ACS Appl. Bio Mater. 5 (2022) 5924–5932. https://doi.org/10.1021/acsabm.2c00870.

[27]

F. Caddeo, D. Loche, M.F. Casula, A. Corrias, Growing CeO₂ Nanoparticles Within the Nano-Porous Architecture of the SiO₂ Aerogel, Front. Chem. 8 (2020) 57. https://doi.org/10.3389/fchem.2020.00057.

[28]

K. Chen, C. Xu, J. Zhou, R. Zhao, Q. Gao, C. Wang, Multifunctional fabric coatings with slow-releasing fragrance and UV resistant properties from ethyl cellulose/silica hybrid microcapsules, Carbohydr. Polym. 232 (2020) 115821. https://doi.org/10.1016/j.carbpol.2019.115821.

[29]

S. Parvate, P. Dixit, S. Chattopadhyay, Superhydrophobic Surfaces: Insights from Theory and Experiment, J. Phys. Chem. B 124 (2020) 1323–1360. https://doi.org/10.1021/acs.jpcb.9b08567.

[30]

R.S. Gabardo, D.S. De Carvalho Cotre, M.J. Lis Aria, M.P. Moisés, B.T. Martins Ferreira, R.B. Samulewski, J.P. Hinestroza, F.M. Bezerra, Surface modification of polyester fabrics by ozone and its effect on coloration using disperse dyes, Materials 14 (2021) 3492. https://doi.org/10.3390/ma14133492.

[31]

K. Liu, L. Jiang, Bio-inspired design of multiscale structures for function integration, Nano Today 6 (2011) 155–175. https://doi.org/10.1016/j.nantod.2011.02.002.

[32]

Y. Peng, T. Li, Recent Developments in the Fabrication and Application of Superhydrophobic Surfaces, Chem. Rec. 24 (2024) e202400065.

[33]

F. Sotoudeh, S.M. Mousavi, N. Karimi, B.J. Lee, J. Abolfazli-Esfahani, M.K.D. Manshadi, Natural and synthetic superhydrophobic surfaces: A review of the fundamentals, structures, and applications, Alex. Eng. J. 68 (2023) 587–609. https://doi.org/10.1016/J.AEJ.2023.01.058.

[34]

F. Liu, X. Di, X. Sun, X. Wang, T. Yang, M. Wang, J. Li, C. Wang, Y. Li, Superhydrophobic/Superoleophilic PDMS/SiO₂ Aerogel Fabric Gathering Device for Self-Driven Collection of Floating Viscous Oil, Gels 9 (2023) 405. https://doi.org/10.3390/gels9050405.

[35]

H. Guo, Y. Wang, H. Zhang, K. An, Recent advances and strategies in mechanical stability of superhydrophobic surfaces, Prog. Org. Coat. 194 (2024) 108595. https://doi.org/10.1016/J.PORGCOAT.2024.108595.

[36]

R.S. Sutar, S.G. Kodag, R.A. Ekunde, A.S. Sawant, T.A. Ekunde, S. Nagappan, Y.H. Kim, V.S. Saji, S. Liu, S.S. Latthe, Durable self-cleaning superhydrophobic cotton fabrics for wearable textiles, Ind. Crops Prod. 222 (2024) 119717. https://doi.org/10.1016/J.INDCROP.2024.119717.

[37]

J.A.B. Valle, R. de C.S. Curto Valle, C. da Costa, F.B. Maestá, M.J. Lis Arias, Reservoir Effect of Textile Substrates on the Delivery of Essential Oils Microencapsulated by Complex Coacervation, Polymers 16 (2024) 670. https://doi.org/10.3390/polym16050670.

[38]

H. Deng, W. Yang, T. Cai, F. He, Y. Li, K. Zhang, R. He, Phase-change composites silicone rubber/paraffin@SiO₂ microcapsules with different core/shell ratio for thermal management, Int. J. Energy Res. 45 (2021) 18033–18047. https://doi.org/10.1002/er.6949.

Downloads

Published

2026-03-09

Issue

Section

Original Research Articles

How to Cite

Islam, M. S., KHURSHID ALAM, MST ATIA RABBI, & Ahmed, S. (2026). IMPARTING SUPERHYDROPHOBICITY OF POLYESTER FABRICS WITH CONTROLLED RELEASE USING SIO2 AEROGEL MICROCAPSULE COATING. Textile Science & Research Journal, 2(1), 15-26. https://doi.org/10.63456/tsrj-2-1-28

Similar Articles

You may also start an advanced similarity search for this article.